Publikace detail

Ansa-vanadocene complexes with short interannular bridge.

Autoři: Honzíček Jan | Paláčková Hana | Císařová Ivana | Vinklárek Jaromír

Rok: 2006

Druh publikace: článek v odborném periodiku

Název zdroje: Journal of Organometallic Chemistry

Strana od-do: 202-207

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Ansa-vanadocene complexes with short interannular bridge.	The new ansa-vanadocene complexes with short interannular bridge (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy.	Ansa-metallocene; vanadocene dichloride; X-ray structural analysis; EPR spectroscopy; antitumor agents
eng	Ansa-vanadocene complexes with short interannular bridge.	The new ansa-vanadocene complexes with short interannular bridge (CH3)2C(C5H4)2VX2 (X = Cl, Br) were prepared, characterized by spectroscopic methods and X-ray structural analysis. It was shown, that connection of cyclopentadienyl rings by dimethylmethane bridge affects the structural parameters. The behavior ansa-vanadocene dichloride in aqueous solution in presence of bio-ligands was studied by EPR spectroscopy.	Ansa-metallocene; vanadocene dichloride; X-ray structural analysis; EPR spectroscopy; antitumor agents

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