Publikace detail

Double O,C,O-chelated diorganotin cation,

Autoři: Dostál Libor | Růžička Aleš | Holeček Jaroslav | Jambor Roman

Rok: 2010

Druh publikace: článek v odborném periodiku

Název zdroje: Inorganic Chemistry Communications

Název nakladatele: Elsevier Science BV

Místo vydání: Amsterdam

Strana od-do: 1470-1472

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	OCO-Disubstituavaný diorganocíničitý kation	The doubly O,C,O-chelated diorganotin(IV) compound L2SnBr2 (1), where L is 2,6-(MeOCH2)2C6H3−, was prepared as a precursor for the synthesis of intramolecularly Sn←O coordinated organotin(IV) cations. Compound 1 spontaneously ionizes in the presence of excess of SnBr4, yielded the double O,C,O-chelated diorganotin(IV) ionic pair [L2SnBr]+ [SnBr5·THF]− (2), the molecular structure of which was elucidated by X-ray diffraction.	OCO-ligand; diorganocíničitý; kation
eng	Double O,C,O-chelated diorganotin cation,	The doubly O,C,O-chelated diorganotin(IV) compound L2SnBr2 (1), where L is 2,6-(MeOCH2)2C6H3−, was prepared as a precursor for the synthesis of intramolecularly Sn←O coordinated organotin(IV) cations. Compound 1 spontaneously ionizes in the presence of excess of SnBr4, yielded the double O,C,O-chelated diorganotin(IV) ionic pair [L2SnBr]+ [SnBr5·THF]− (2), the molecular structure of which was elucidated by X-ray diffraction.	O,C,O-ligand; diorganotin; cation

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