Publikace detail

NCN-Chelated Organoantimony(III) and Organobismuth(III) Phosphates: Synthesis and Solid-State and Solution Structures.

Rok: 2011

Druh publikace: článek v odborném periodiku

Název zdroje: Inorganic Chemistry

Název nakladatele: American Chemical Society

Místo vydání: Washington

Strana od-do: 6411-6413

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	NCN-chelatované organoantimonité a bismutité fosfáty	Byly připraveny organoantimonité a bismutité fosfáty (LM)3(PO4)2 [M = Sb (3) a Bi (4)] obsahující NCN-chelátující ligand L [L = 2,6-(CH2NMe2)2C6H3]. Tyto sloučeniny byly připraveny reakcí odpovídajících oxides s H3PO4.	organoantimon;organobismut;fosfáty
eng	NCN-Chelated Organoantimony(III) and Organobismuth(III) Phosphates: Synthesis and Solid-State and Solution Structures.	Organoantimony(III) and organobismuth(III) phosphates (LM)3(PO4)2 [M = Sb (3) and Bi (4)], containing the NCN-chelating ligand L [L = 2,6-(CH2NMe2)2C6H3], were prepared by the simple treatment of parent oxides 1 and 2 withH3PO4. Both compounds were characterized by elemental analysis, electrospray ionization mass spectrometry, and IR and NMR spectroscopy and in the case of 3 by X-ray diffraction techniques. Compound 3 has an interesting behavior in solution, i.e., the formation of two possible conformational isomers, which was studied by 1H, 13C, and 31P NMR spectroscopy.	Organoantimony(III);Organobismuth(III);Phosphates

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