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SYNTHESIS OF D-p-A-p-D SYSTEMS BASED ON INDAN-1,3-DIONE
Autoři: Solanke Parmeshwar Bapurao | Bureš Filip
Rok: 2012
Druh publikace: ostatní - přednáška nebo poster
Strana od-do: nestránkováno
Tituly:
Jazyk Název Abstrakt Klíčová slova
eng SYNTHESIS OF D-p-A-p-D SYSTEMS BASED ON INDAN-1,3-DIONE The design of nonlinear optical (NLO) molecules has become a focus of current research in view of their potential applications in various photonic technologies. Materials with NLO activity found use as electro-optic switching elements for telecommunication and optical information processing. A typical organic push-pull chromophore with second-order nonlinear optical (NLO) properties consists of an electron donor and an electron acceptor interacting through a p-conjugated spacer. Indan-1,3-dione and 3-dicynomethylidene-1-indanone have been chosen as main acceptor moieties of the proposed organic D-p-A-p-D systems. This strong acceptor system was further modified by electron donors such as N,N-dimethylamino group either on C2 or the fused benzene ring. The donor groups were linked to the benzene ring through the p-linkers of various shapes and lengths in order to finely tune the NLO properties. indan-1,3-dione; chromophore; D-p-A-p-D systems