Publikace detail

Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds

Rok: 2012

Druh publikace: článek v odborném periodiku

Název zdroje: European Journal of Inorganic Chemistry

Název nakladatele: Wiley-VCH

Místo vydání: Weinheim

Strana od-do: 2578-2587

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Syntéza, struktura a transmetalační aktivata C,Y-chelatovaných organozlatných sloučenin	Byly připraveny a charakterizovány C,Y-chelatované organozlatné sloučeniny. Tyto sloučeniny byly dále studovány jako vhoné prekurzory pro transmetalační reakce.	Syntéza, struktura a transmetalační aktivita různých C,Y-chelátů organozlatných sloučenin
eng	Synthesis, Structure and Transmetalation Activity of Various C,Y-Chelated Organogold(I) Compounds	A set of organogold(I) compounds L14Au(PPh3), where L1 = [o-C6H4(CH=NC6H3iPr2-2,6)] (1), L2 = {o,o-C6H3[C(Me)=NC6H3Me2-2,6]2} (2), L3 = [o,o'-C6H3(CH2OMe)(CH2NMe2)] (3), L4 = [o,o-C6H3(CH2OMe)2] (4), were synthesized by the reaction of parent organolithium derivatives L14Li with [AuCl(PPh3)] in good yields. The molecular structures of 14 were characterized by ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and their structures in the solid state were determined using single-crystal X-ray diffraction analyses. The transmetalation potential of 14 was tested by the reaction with either [PdCl2(CH3CN)2] or [PtCl2(Et2S)2] complexes. While the reaction of compounds 1 and 2 proceeded smoothly with the formation of the desired transition-metal complexes, i.e. (L1PdCl)2 (5), L1PtCl(Et2S) (6) and L2MCl [M = Pd (7) or Pt (8). In the case of the O,C,N- and O,C,O-chelated derivatives 3 and 4 only the platinum(II) compounds L3PtCl(PPh3) (9) and L4PtCl(Et2S)2 (10) could be isolated after the reaction, as a result of the labile behaviour of the corresponding palladium compounds. All derivatives 510 were characterized by the help of ESI mass spectrometry and 1H NMR, 13C NMR and 31P NMR spectroscopy, and in the case of compounds 57 and 9 using single-crystal X-ray diffraction analyses.	Synthesis; Structure; and; Transmetalation; Activity; Various; C,Y-Chelated; OrganogoldI; Compounds

Vyhledávání

Přihlášení pro studenty

Přihlášení pro zaměstnance

Publikace detail

Katedry

Ústavy a pracoviště

Jak nás najdete?

Služby

Často hledáte