Publikace detail

Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration

Rok: 2012

Druh publikace: článek v odborném periodiku

Název zdroje: Dalton Transactions

Název nakladatele: Royal Society of Chemistry

Místo vydání: Cambridge

Strana od-do: 5140-5143

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Monomerní organoantimonitý sulfid a selenid	NCN chelatované monomerní chalkogenidy LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl) byly připraveny a obsahují terminální vazbu Sb-Se a Sb-S.	hlavní sklupina prvků, kovalentní poloměr, jednoduchá vazba, DIPNICTENES, ligandy
eng	Monomeric organoantimony(III) sulphide and selenide with terminal Sb-E bond (E = S, Se). Synthesis, structure and theoretical consideration	NCN chelated monomeric chalcogenides, LSbE (E = S (1), Se (2), L = 2,6-bis[N-(2',6'-dimethylphenyl)ketimino]phenyl), were synthesized and characterized with the help of elemental analysis, NMR spectroscopy and single-crystal X-ray diffraction analyses. The terminal Sb-E (E = S, Se) bonds in 1 and 2 were subjected to theoretical investigation and the results are compared with the hypothetical molecules, PhSb=E (E = S, Se, Te), and earlier reported analogues.	MAIN-GROUP ELEMENTS; COVALENT RADII; SINGLE-BOND; DIPNICTENES; LIGANDS

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