Publikace detail

Magnesium, aluminium and zinc compounds containing hybrid amino-amide ligand

Autoři: Kampová Hana | Riemlová Emílie | Klikarová Jitka | Růžička Aleš | Padělková Zdeňka

Rok: 2013

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Magnesium, aluminium and zinc compounds containing hybrid amino-amide ligand	Series of reactions of 2-[(N,N-dimethylamino)methyl]phenylamine (LNNH2) [1] or its substituted form, 2-[(N,N-dimethylamino)methyl]phenyl(trimethylsilyl)amine (LNN(SiMe3)H), with diorganomagnesium(II) and organomagnesium(II) halides, trimethylaluminium and dimethylaluminium chloride, methylaluminium dichloride and diethylzinc were performed. All products were characterized by the help of NMR spectroscopy. Only few examples of magnesium(II) and aluminium(III) amides structures have been described in the literature so far [2]. Some products of the above mentioned reactions were characterized by means of X-ray diffraction techniques. The molecular structure of the described compounds reveals a four-coordinated central metal atom (Mg(II) or Al(III)).

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