Univerzita PardubiceFakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Reactivity of (organo)magnesium species towards selected carbodiimides

Autoři: Weidlich Tomáš | Chlupatý Tomáš | Růžička Aleš

Rok: 2013

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Reactivity of (organo)magnesium species towards selected carbodiimides	Nowadays, the main interest in the chemistry of both guanidinates and amidinates is focused on the complexation and stabilization of unusual, generally lower, oxidation states of metals. The current topic in this chemistry, in the class of the main group metal compounds, is the synthesis, structural studies and reactivity with pointing towards preparation of reduced silicon, germanium and tin species. This particular topic is mainly followed by Roesky, Jones and others [1]. Our contribution to this area of chemistry concerns the plausible synthesis and characterization of novel lithium n-butyl amidinates [2]. This work was followed by other paper which describes the addition of Lappert's stannylenes to carbodiimides providing a new class of tin(II) guanidinates [3]. Our recent work is focused to the feasible addition of magnesium species (e.g. Grignard reagents and others as well) to the very backbone of selected carbodiimides as shown in Scheme 1. Further reactivity studies of various (organo)magnesium reagents towards selected carbodiimides will be presented. Structural characterization of prepared compounds will be discussed in detail, too.	Main; group; metal; complexes; hybrid; amidinate; guanidinate; ligands