Univerzita PardubiceFakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Comparison of N,N-chelating amides containing group 14 metal compounds

Autoři: Kampová Hana | Růžička Aleš | Padělková Zdeňka

Rok: 2013

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Comparison of N,N-chelating amides containing group 14 metal compounds	The chelating [2-(dimethylamino)methyl]phenyl- ligand with the pendant amino group was successfully used in order to stabilize low valent group 14 metals forming thus the five-membered azametalla cycle via a formation of a hemilabile intramolecular connection. These compounds are well explored now, so we decided to study [2-(dimethylamino)methyl]aniline as a ligand containing both amido functionality available for rather strong metal to nitrogen covalent bond and the pendant amino group for the creation of six-membered diazametalla cycle.1 Non-substituted (A), trimethylsilyl- or triphenylgermyl- (B) and benzyl- (C) substituted compounds will be compared.	N,N-chelating; amides; metal