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Publikace detail

Ferrocene as donor part in push pull chromophores
Autoři: Kousalová Jana | Kulhánek Jiří
Rok: 2014
Druh publikace: ostatní - přednáška nebo poster
Strana od-do: nestránkováno
Tituly:
Jazyk Název Abstrakt Klíčová slova
eng Ferrocene as donor part in push pull chromophores The objective of this work is synthesis and study of properties of new push-pull chromophores on the based of ferrocene, which was used as donor part. Thiophene with combination with double or triple bond was used as π-linkage. As acceptor were used 1-methylimidazol-4,5-dicarbonitrile, 5-cyanothiophene or 3,4-dicyanothiophene. Three series of push-pull chromophores were prepared which different acceptor group. Compounds (13-15) with changed of type of π-linkage were prepared in each series. Synthesis was carried out three to five steps with the use of Suzuki-Miyaura, Sonogashira or Heck cross-coupling reaction. The electrochemistry properties of prepared push-pull chromophores were measured. Push-pull chromophores, cross-coupling, ferrocene