Publikace detail

Coordination compounds of 2-[(N,N-dimethylamino)methyl]anilide with aluminium, magnesium and zinc

Autoři: Kampová Hana | Riemlová Emilie | Klikarová Jitka | Padělková Zdeňka | Růžička Aleš

Rok: 2014

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Coordination compounds of 2-[(N,N-dimethylamino)methyl]anilide with aluminium, magnesium and zinc	Reactions of 2-[(N,N-dimethylamino)methyl]aniline (LNNH2) or its substituted forms, 2-[(N,N-dimethylamino)methyl]phenyl(trimethylsilyl)amine (LNN(SiMe3)H) and 2-[(N,N-dimethylamino)methyl]phenyl(benzyl)amine (LNN(Bz)H) with trimethylaluminium, dimethylaluminium chloride, diorganomagnesium(II) and diethylzinc were realized. All products were characterized by multinuclear NMR spectroscopy. Group of N,N-chelated aluminium(III), magnesium(II) and zinc(II) amides structures is rather rare. Some of these products of above mentioned reactions were characterized by the XRD analysis., Central metal atom (Al, Mg and Zn) is four coordinated in all mentioned cases.

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