Publikace detail

Sn, Mg, and Zn based species: Catalytic activity studies within the synthesis of polyethylene terephthalate.

Autoři: Hubená Petra | Švec Petr | Růžičková Zdeňka | Růžička Aleš | Merna Jan

Rok: 2014

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Sn, Mg, and Zn based species: Catalytic activity studies within the synthesis of polyethylene terephthalate.	A series of some C,N-chelated diorganotin(IV) species (e.g. (LCN)2Sn(OCH2CH2O), LCNBuSn(OCH2CH2O), (LCN)2Sn(1,2-O2-3,5-t-Bu2C6H2), and LCNBuSn(1,2-O2-3,5-t-Bu2C6H2)) was prepared in the term of this work.1,2 One of them, LCNBuSn(OCH2CH2O), is an original compound which has not been described in the literature yet. Two other Mg and Zn based species were synthesized as well. All prepared compounds were characterized by elemental analysis and multinuclear NMR spectroscopy. Moreover, the molecular structure of novel LCNBuSn(OCH2CH2O) was determined by XRD techniques. Catalytic activity studies of these species within the synthesis of polyethylene terephthalate (PET) from dimethyl terephthalate and ethylene glycol were carried out. All synthetic aspects as well as characterization of prepared polymers will be discussed in detail.

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