Univerzita Pardubice Fakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Tuning properties of push-pull molecules

Autoři: Bureš Filip

Rok: 2015

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Tuning properties of push-pull molecules	Organic molecules with all pi-conjugated scaffolds are currently tremendously investigated organic materials. Such molecules can be widely found in (opto)electronic devices such as nonlinear optical (NLO) materials and memories, organic light-emitting diodes (OLEDs), dye-sensitizing solar cells (DSSCs), semiconductors, switches and many others. Moreover, in a pi-conjugated system end-capped with electron donors D (e.g. NR2 or OR groups) and electron acceptors A (e.g. NO2 or CN groups) intramolecular charge-transfer (ICT) from the donor via pi system to the acceptor occurs. Such dipolar push-pull molecules represent unique class of compounds with distinct optical and electrochemical properties. In our continuing synthetic efforts, we have developed several series of organic push-pull D-pi-A systems and have thoroughly investigated and reviewed their structure-property relationships. In general, the property tuning of push-pull chromophores can be achieved by the modification of the electronic nature of appended donors and acceptors as well as variation of the pi-linker. Brief synthesis of several representative derivatives and tailoring of their electronic properties will be discussed.	push-pull molecules, structure-property relationships, optical properties, electrochemical properties, intramolecular charge-transfer