Univerzita PardubiceFakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Study of reactivity of germylene stabilized by boraguanidinate ligand

Autoři: Böserle Jiří | Dostál Libor

Rok: 2015

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Study of reactivity of germylene stabilized by boraguanidinate ligand	The investigation dealing with reactivity of germylene 1 containing in its structure a boraguanidinate ligand is presented. This type of dianionic N,N’-chelating ligands is derived from guanidinate ligands by a substitution a carbon atom by a boron atom and represents a relatively unexplored branch of organometallic chemistry.The electronic and steric properties of these ligands may be fine-tuned by the use of different substituents on the BN3 backbone. Another interesting property of these ligands is dianionic character which significantly affects their reactivity. Herein, we report on the synthesis of the rare example of boraguanidinate-stabilized germylene 1 and its reactivity with selected reagents. Observed results show that 1 may be a promising candidate for activation of various compounds especially small molecules.