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Intercalates of Porphyrines with Zirconium Sulfophenylphosphonates: Relation Between Their Structure, Optical Properties and Amount of Sulfogroups

Rok: 2016

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Intercalates of Porphyrines with Zirconium Sulfophenylphosphonates: Relation Between Their Structure, Optical Properties and Amount of Sulfogroups	Intercalation of 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine and zinc 5,10,15,20-tetra(4-pyridyl)-21H,23H-porphine into three mixed zirconium sulfophenylphosphonates is described. All three hosts are able to intercalate both porphyrins, the amount of intercalated guests and their orientation depends on the amount of acidic groups. Porphyrin molecules are not aggregated in the intercalates, they exhibit fluorescence and are able to generate singlet oxygen.	zirkonium phosphonates; porphyrine; intercalation

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