Publikace detail

From Simple Precursors to Interesting Heterocyclic Compounds Containing Heavier Group 14 and 15 Elements.

Autoři: Dostál Libor | Kořenková Monika | Kremláček Vít | Böserle Jiří

Rok: 2017

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	From Simple Precursors to Interesting Heterocyclic Compounds Containing Heavier Group 14 and 15 Elements.	We have been involved in the investigation of low-valent Group 15 compounds, especially monomeric pnictinidenes, for quite a long time. We have utilized N,C,N-pincer type ligands for their stabilization and we have also demonstrated that they may be used as ligands for a variety of transition metal compounds. Very recently, we have focused on the reactivity of these and related systems with unsaturated systems. Similarly, we have recently reported synthesis and preliminary reactivity of boroguanidinato-stabilized germylene. Nowadays, we are targeting the reactivity of the germylene with various alkynes giving, besides expected cyclodigermabutenes, interesting heterocyclic compounds.	Heterocyclic Compounds; Heavier Group 15 Elements; Alkynes; Germanium; Germylenes;

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