Publikace detail

Beyond The Hetero-Diels-Alder reaction. New horizons in reactivity of heavier Pnictinidenes with unsaturated Molecules

Autoři: Dostál Libor | Zechovský Jan | Hejda Martin

Rok: 2022

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Beyond The Hetero-Diels-Alder reaction. New horizons in reactivity of heavier Pnictinidenes with unsaturated Molecules	The activation of various molecules by so-called ligand-metal cooperation1 found widespread application in the field of catalysis using transition metals. This concept has been recently extended and applied in the field of p-block elements as well.2 We have recently demonstrated that the pincer ligand stabilized pnictinidenes exhibit an aromatic character and can be regarded as azapnictoles. We have used them as latent heterodienes and showed that they are able to activate various chemical bonds including C-C multiple bonds resembling classical Diels-Alder reaction protocol.3 Recently, we have discovered that the formation of Diels-Alder adducts is not a necessary end of the story, but these compounds exhibit remarkable follow-up chemistry. The up-to-date achievements and advances in the field will be presented and discussed.

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