Publikace detail

Hybrid guanidinates as versatile ligands for early transition metal catalysts

Autoři: Gira Natália | Horáček Michal | Pokorná Kristýna | Varga Vojtech

Rok: 2022

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Hybrid guanidinates as versatile ligands for early transition metal catalysts	Guanidines and their anionic forms guanidinates attract a lot of attention in recent years thanks to their extraordinary ability to sterically and electronically stabilize the central atom in the complex as a result of unlimited possibilities of adapting their steric hindrance and electronic properties through the variation of substituents on nitrogen atoms The donor properties and diversity of coordination modes make them compatible with virtually any metal or non metal atom. Therefore, compounds combining hybrid guanidinate and cyclopentadienyl ligand in the metal coordination sphere are expected to have catalytic activity in C C bond formation reactions.

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