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An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway
Autoři: Criado José Manuel | Pérez-Maqueda Luis A. | Gotor Francisco José | Málek Jiří | Koga Nobuyoshi
Rok: 2003
Druh publikace: článek v odborném periodiku
Název zdroje: Journal of Thermal Analysis and Calorimetry
Název nakladatele: Springer
Strana od-do: 901-906
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway The Ozawa concept of generalized time has been used for developing master plots for the different kinetic models describing solid state reactions. These plots can be indistinctly used for analysing isothermal or non-isothermal experimental data. It is demonstrated that it is not possible to discriminate the kinetic model from a single non-isothermal curve without a previous knowledge of the activation energy. xxxxx
eng An Unified Theory for the Kinetic Analysis of Solid State Reactions under Any Thermal Pathway The Ozawa concept of generalized time has been used for developing master plots for the different kinetic models describing solid state reactions. These plots can be indistinctly used for analysing isothermal or non-isothermal experimental data. It is demonstrated that it is not possible to discriminate the kinetic model from a single non-isothermal curve without a previous knowledge of the activation energy. solid state reactions, theory for the kinetic analysis, thermal pathway