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Publikace detail

Structural Relaxation of Amorphous Ge38S62 Studied by Length Dilatometry and Calorimetry
Rok: 2003
Druh publikace: článek v odborném periodiku
Název zdroje: Journal of Thermal Analysis and Calorimetry
Název nakladatele: Springer
Strana od-do: 355-362
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze Strukturální relaxace amorfního Ge38S62 studovaná pomocí dilatometrie a kalorimetrie The structural relaxation of Ge38S62 glass has been studied by length dilatometry and calorimetry. The Tool-Narayanaswamy-Moynihan model was applied on obtained data of structural relaxation and parameters of this model were determined: Dh*=483?2 kJ/mol, ln(A/s)=-81?1, b=0.7?0.1 and x=0.6?0.1. Both dilatometric and calorimetric relaxation data were compared on the basis of the fictive relaxation rate. It was found that the relaxation rates are very similar and well correspond to the prediction of phenomenological model. chalkogenidová skla;objemová relaxace;entalpická relaxace;germanium-síra
eng Structural Relaxation of Amorphous Ge38S62 Studied by Length Dilatometry and Calorimetry The structural relaxation of Ge38S62 glass has been studied by length dilatometry and calorimetry. The Tool-Narayanaswamy-Moynihan model was applied on obtained data of structural relaxation and parameters of this model were determined: Dh*=483?2 kJ/mol, ln(A/s)=-81?1, b=0.7?0.1 and x=0.6?0.1. Both dilatometric and calorimetric relaxation data were compared on the basis of the fictive relaxation rate. It was found that the relaxation rates are very similar and well correspond to the prediction of phenomenological model. Chalcogenide Glasses;Volume Relaxation;Enthalpy Relaxation;Germanium-Sulphur