Publikace detail

New Aspects of Impact Reactivity of Polynitro Compunds. Part IV. Allocation of Polynitro Compounds on the Basis of their Impact Sensitivities.

Autoři: Zeman Svatopluk

Rok: 2003

Druh publikace: článek v odborném periodiku

Název zdroje: Propellants Explosives Pyrotechnics

Název nakladatele: Wiley-VCH

Místo vydání: Weinheim

Strana od-do: 308-313

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze			impact sensitivity, polynitro compounds
eng	New Aspects of Impact Reactivity of Polynitro Compunds. Part IV. Allocation of Polynitro Compounds on the Basis of their Impact Sensitivities.	A linear relationship has been found between the drop energies of impact sensitivity detected by sound and the drop energies of ?the first reaction? for 28 polynitro compounds. In the sense of this relationship, the compounds studied fall into three classes. The reason of the said diversification lies in the decomposition reaction rate at the temperature of beginning of their thermolysis. It is stated that some relationship exists between vibrational excitation by impact, on the one hand, and thermal activation of the molecules of energetic materials, on the other.	impact sensitivity, polynitro compounds

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