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Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony ? Selenium and -Tellurium Terminal Bonds.
Autoři: Dostál Libor | Jambor Roman | Růžička Aleš | Lyčka Antonín | Brus Jiří | de Proft Frank
Rok: 2008
Druh publikace: článek v odborném periodiku
Název zdroje: Organometallics
Název nakladatele: American Chemical Society
Místo vydání: Washington
Strana od-do: 6059-6062
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony-Selenium and -Tellurium Terminal Bonds The reactions of the organoantimony(I) compound Sb4Ar4 (Ar = N,C,N chelating ligand, C6H3-2,6-(CH2NMe2)2) with elemental Se and Te give unprecedented monomeric compounds ArSbE (E = Se, Te) with the terminal Sb-E bond being retained both in solution and in the solid state. antimon, selen, tellur, oxidace, násobné vazby, krystalová struktura, NMR spektroskopie
eng Synthesis and Structure of Organoantimony(III) Compounds Containing Antimony ? Selenium and -Tellurium Terminal Bonds. The reactions of the organoantimony(I) compound Sb4Ar4 (Ar = N,C,N chelating ligand, C6H3-2,6-(CH2NMe2)2) with elemental Se and Te give unprecedented monomeric compounds ArSbE (E = Se, Te) with the terminal Sb-E bond being retained both in solution and in the solid state. antimony, selenium, tellurium, oxidation, multiple bonds, X-ray structure, NMR spectroscopy