Publikace detail

Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides.

Rok: 2007

Druh publikace: článek v odborném periodiku

Název zdroje: Journal of Fluorine Chemistry

Název nakladatele: Elsevier Science SA

Místo vydání: Lausanne

Strana od-do: 1390-1395

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides.	The tin atom in the solid-state structure of {2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.
eng	Structure of C,N-chelated nButyltin(IV) fluorides and their use as fluorating agents of some chlorosilanes, chlorophosphine and metal halides.	The tin atom in the solid-state structure of {2-[(CH3)2NCH2]C6H4}nBu2SnF is five coordinated with carbon atoms in equatorial and fluorine and nitrogen atoms in axial positions. The fluorination of {2-[(CH3)2NCH2]C6H4}nBuSnCl2 is described by NMR methods. The successful attempts to fluorinate various chlorosilanes, chlorophosphine and metal halides are also reported.	Organotin(IV) fluorides; C,N-ligand; Structure

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