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Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II)
Autoři: Potočnák I | Lancz G | Růžička Aleš | Jaeger I
Rok: 2007
Druh publikace: článek v odborném periodiku
Název zdroje: Acta Crystallographica Section E - Structure Reports Online
Název nakladatele: International Union of Crystallography
Strana od-do: m2072
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II) The crystal structure of the title complex, [Ni(C4N3)(2)(C6H18N4)], is made up of neutral mononuclear [Ni(tren){C(CN)(3)}(2)] units [tren = tris(2-aminoethyl)amine] which are linked through van der Waals interactions and N-H center dot center dot center dot N hydrogen bonds. The Ni atom has a distorted octahedral coordination environment, bonded to the four tren N atoms [average Ni-N = 2.096 (17) angstrom] and the two cis-positioned C(CN)(3) N atoms [Ni-N = 2.045 (4) and 2.118 (4) angstrom].
eng Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II) The crystal structure of the title complex, [Ni(C4N3)(2)(C6H18N4)], is made up of neutral mononuclear [Ni(tren){C(CN)(3)}(2)] units [tren = tris(2-aminoethyl)amine] which are linked through van der Waals interactions and N-H center dot center dot center dot N hydrogen bonds. The Ni atom has a distorted octahedral coordination environment, bonded to the four tren N atoms [average Ni-N = 2.096 (17) angstrom] and the two cis-positioned C(CN)(3) N atoms [Ni-N = 2.045 (4) and 2.118 (4) angstrom]. Cis-Bistricyanomethanido ? kappa N)tris(2-aminoethyl)amine-kappa N-4)nickel(II)