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Use of C,N-chelated Organotin(IV) Fluorides as Fluorinating Agens
Autoři: Švec Petr | Růžička Aleš
Rok: 2007
Druh publikace: ostatní - přednáška nebo poster
Strana od-do: nestránkováno
Tituly:
Jazyk Název Abstrakt Klíčová slova
cze Use of C,N-chelated Organotin(IV) Fluorides as Fluorinating Agens Structure of C,N-chelated organotin(IV) fluorides has been studied well both in solution and solid state in our department.1,2 The intramolecular coordination of nitrogen atom to the tin atom led to activation of Sn-F bond. This activation makes possible to use these compounds as very efficient and mild fluorinating agent. Some fluorination experiments of organochlorophosphine, organochlorosilanes and inorganic halides will be discussed.
eng Use of C,N-chelated Organotin(IV) Fluorides as Fluorinating Agens Structure of C,N-chelated organotin(IV) fluorides has been studied well both in solution and solid state in our department.1,2 The intramolecular coordination of nitrogen atom to the tin atom led to activation of Sn-F bond. This activation makes possible to use these compounds as very efficient and mild fluorinating agent. Some fluorination experiments of organochlorophosphine, organochlorosilanes and inorganic halides will be discussed. Use of C,N-chelated Organitin(IV) Fluorides as Fluorinating Agens