Publikace detail

Reactivity of Organotin(I) Dimers RSnSnR (R = 2,6-(Me2NCH2)2C6H3, 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2) with Diaryl Dichalcogenides, ArEEAr (E = S, Se, Te; Ar = Ph, 2-C5H4N): Control of Secondary Sn???Sn Interactions by Intramolecular Coordination and Identity of the Aryl Chalcogenate

Rok: 2013

Druh publikace: článek v odborném periodiku

Název zdroje: Organometallics

Název nakladatele: American Chemical Society

Místo vydání: Washington

Strana od-do: 4973-4984

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Reaktivita Organocínatých sloučenin RSnSnR (R = 2,6-(Me2NCH2)2C6H3, 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2) s diaryl dichalcogenides ArEEAr (E = S, Se, Te; Ar = Ph, 2-C5H4N)	Reakce in situ připravených sloučenin RSnSnR s diaryl dichalkogenidy ArEEAr vedly ke vzniku intramolekulárně koordinovaných organocínatých chalkogenoarylátů RSnEAr (1, R = 2,6-(Me2NCH2)2C6H3, E = S, Ar = Ph; 2, R = 2,6-(Me2NCH2)2C6H3, E = Se, Ar = Ph; 3, R = 2,6-(Me2NCH2)2C6H3, E = Te, Ar = Ph; 6, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2, E = Se, Ar = Ph; 7, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2, E = Te, Ar = Ph; 8, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2, E = Se, Ar = 2-C5H4N). Sloučeniny byly identifikovány pomocí NMR spektroskopie.	Reaktivita; Organocínaté sloučeniny; distannyny RSnSnR; diaryl dichalkogenidy
eng	Reactivity of Organotin(I) Dimers RSnSnR (R = 2,6-(Me2NCH2)2C6H3, 4-t-Bu-2,6-{P(O)(O-i-Pr)2}2C6H2) with Diaryl Dichalcogenides, ArEEAr (E = S, Se, Te; Ar = Ph, 2-C5H4N): Control of Secondary Sn???Sn Interactions by Intramolecular Coordination and Identity of the Aryl Chalcogenate	The reactions of the in situ prepared organotin(I) compounds RSnSnR with diary! dichalcogenides ArEEAr provided, depending on the ratio of the reactants, the intramolecularly coordinated heteroleptic organotin(II) chalcogenoarylates RSnEAr (1, R = 2,6-(Me2NCH2)(2)C6H3, -E = S, Ar = Ph; 2, R = 2,6-(Me2NCH2)(2)C6H3, E = Se, Ar = Ph; 3, R = 2,6(Me2NCH2)(2)C6H3, E Te, Ar = Ph; 6, R = 4-t-Bu-2,6-{P(O)(O-i-ET)z}(2)C6H2, E = Se, Ar = Ph; 7, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)(2)}(2)C6H2, E = Te, Ar = Ph; 8, R = 4-t-Bu-2,6-{P(O)(O-i-Pr)(2)}(2)C6H2, E = Se, Ar = 2-C5H4N) and the corresponding organotin(IV) compounds RSn(EAr)(3) (4, R = 2,6-(Me2NCH2)(2)C6H3, E = S, Ar = Ph; 5, R = 2,6-(Me2NCH2)(2)C6H3, E = Se, Ar = Ph; 10, R = 4-t-Bu-2,6-{P(O)(O-i-PO2}(2)C6H2, E = S, Ar = 2-C5H4N), respectively. Compound 1O undergoes a thermally initiated cyclization reaction to give the benzoxaphosphastannole derivative {1(P),3(Sn)-Sn(S-Py)2-OP(O)(O-i-Pr)-6-t-Bu-4-P(O)(Oi-Pr)2}C6H2 (11). The compounds were characterized by H-1, C-13, P-31,Sn-119, and Te-125 NMR and IR spectroscopy, electrospray ionization mass spectrometry, and single-crystal X-ray diffraction analysis. The intramolecular Sn-N and Sn-O distances range between 2.501(3) (2) and 2.815(3) angstrom (4) and between 2.407(2) (8 center dot C7H8) and 2.497(2) angstrom, respectively. Compounds 6 and 7 show intermolecular secondary Sn center dot center dot center dot Sn interactions at distances of 3.8876(3) and 3.8379(5) A, respectively.	Organotin(I); Diaryl dichalcogenides; Secondary Sn???Sn Interactions; Intramolecular coordination;

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