Publikace detail

Synthesis and Structure of (N,)C,N-chelated Organoantimony(III) and Bismuth(III) Cations and Isolation of Their Adducts with Ag[CB11H12]

Rok: 2016

Druh publikace: článek v odborném periodiku

Název zdroje: Zeitschrift für anorganische und allgemeine Chemie

Název nakladatele: Wiley-VCH

Místo vydání: Weinheim

Strana od-do: 1212-1217

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Syntéza antimonitých a bismutitých kationtů. Isolace jejich aduktů s Ag[CB11H12]	Byla studována reakce N,C,N-chelatovaných antimonitých a bismutitých chloridů [C6H3-2,6-(CH=NR)(2)]MCl2 [R = tBu a M = Sb (1) a Bi (2); R = Dmp a M = Sb (3) a Bi (4)] (Dmp = 2,6-Me2C6H3) s Ag[CB11H12].	antimon; bismut; kationty
eng	Synthesis and Structure of (N,)C,N-chelated Organoantimony(III) and Bismuth(III) Cations and Isolation of Their Adducts with Ag[CB11H12]	The treatment of N,C,N-chelated antimony(III) and bismuth(III) chlorides [C6H3-2,6-(CH=NR)(2)]MCl2 [R = tBu and M = Sb (1) or Bi (2); R = Dmp and M = Sb (3) or Bi (4)] (Dmp = 2,6-Me2C6H3) with one molar equivalent of Ag[CB11H12] led to a smooth formation of corresponding ionic pairs {[C6H3-2,6-(CH= NR)(2)]-MCl}(+)[CB11H12](-)[R = tBu and M = Sb (7) or Bi (8), R = Dmp and M = Sb (9) or Bi (10)]. Similarly, the reaction of C, N-chelated analogues [C6H2-2-(CH= NDip)-4,6-(tBu)(2)]MCl2 [M = Sb (5) or Bi (6), Dip = 2',6'-iPr(2)C(6)H(3)] gave compounds {[C6H2-2-(CH= NDip)-4,6-(tBu)(2)]MCl}(+)[CB11H12]-[M = Sb (11) or Bi (12)]. All compounds 7-12 were characterized with H-1, B-11 and C-13{H-1} NMR spectroscopy, ESI-mass spectrometry, IR spectroscopy, and molecular structures of 7-9 and 12 were determined by the help of single-crystal X-ray diffraction analysis. In contrast, all attempts to cleave also the second M-Cl bond in 7-12 using another molar equivalent Ag[CB11H12] remained unsuccessful. Nevertheless, the reaction between 7 (or 8) and Ag[CB11H12] produced unprecedented adducts of both reagents namely {[C6H3-2,6-(CH= NtBu)(2)] SbCl}(2)(2+)[Ag-2(CB11H12)(4)](2-) (13) and {[C6H3-2,6-(CH= NtBu)(2)] BiCl}(+)[Ag(CB11H12)(2)](-) (14) in a reproducible manner. The molecular structures of these sparingly soluble compounds were determined by single-crystal X-ray diffraction analysis.	Antimony; Bismuth; Cations; Carboranes; Agostic interactions

Search

Přihlášení pro studenty

Přihlášení pro zaměstnance

Publikace detail

Katedry

Ústavy a pracoviště

Jak nás najdete?

Služby

Často hledáte