Publikace detail

Doubly deprotonable multiple heteroatom donors containing ligand for complexation of various metals

Autoři: Vránová Iva | Bachurina Darya | Storoženková Lenka | Růžička Aleš

Rok: 2017

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Doubly deprotonable multiple heteroatom donors containing ligand for complexation of various metals	Five-membered chelate rings of the type C2N2M belong to the most common structural motifs in coordination chemistry ranging from simple ethylenediamine complexes to complicated clusters. The change of substituents of the nitrogen atoms offers simple tuning of both steric and electronic properties of each ligand. Over the last decade, ligands bearing phosphane moieties have caught considerable attention mostly in transition metal chemistry.1However, possibility to introduce additional donor moieties in the form of chalcogen atom was described only scarcely in the literature.2,3 Herein, we report on preparation of novel ligand precursor (Scheme 1) and its use for preparation of complexes with main group metals. Further reactivity will be studied as well.

Search