Publikace detail

Stabilization of two coordinate tetrylene by borylamide ligand

Autoři: Aman Michal | Mrózek Ondřej | Dostál Libor | Růžičková Zdeňka | Jambor Roman

Rok: 2018

Druh publikace: článek v odborném periodiku

Název zdroje: Journal of Organometallic Chemistry

Název nakladatele: Elsevier Science BV

Místo vydání: Amsterdam

Strana od-do: 1-7

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Stabilizace dvoukoordinovaných tetrylenů	Byly připraveny aminoboranový ligand HN(BCy2) (C6H3-2,6-Me-2) (1) (Cy = cyclohexyl) a také jeho deriváty {E [N(BCy2) (C6H3-2,6-Me-2)](2)} (E = Sn (4), Pb (5)).	Stabilizace; tetryleny; NMR spektroskopie
eng	Stabilization of two coordinate tetrylene by borylamide ligand	Here we report the synthesis of aminoborane HN(BCy2) (C6H3-2,6-Me-2) (1) (Cy = cyclohexyl), that was successfully deprotonated and its lithium salt {LiN(BCy2) (C6H3-2,6-Me-2)}(2) (2) has been characterised. The borylamide ligand -N(BCy2) (C6H3-2,6-Me-2) was used for the preparation of N -> Sn coordinated stannylene [2,6-(Me2NCH2)(2)C6H3]Sn [N(BCy2) (C6H3-2,6-Me-2)] (3) and two coordinate tetrylenes {E [N(BCy2) (C6H3-2,6-Me-2)](2)} (E = Sn (4), Pb (5)). Experimental and theoretical studies suggested sigma character of E-N bonds without additional N(p)-> E(p) donation as the result of the preference of N(p)-> B(p) donation in 4 and 5. DFT studies on 4 and 5 also reveal theirs HOMO to exhibit E lone pair character and theirs LUMO to include p-orbital character located on metal atoms E. (C) 2018 Elsevier B.V. All rights reserved.	Low coordination; Chelating ligand; Tetrylenes; NMR spectroscopy; DFT calculations

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