Publikace detail

Pyroaurite-based Mg-Fe mixed oxides and their activity in aldol condensation of furfural with acetone: effect of oxide composition

Autoři: Kocík Jaroslav | Frolich Karel | Perková Ilona | Horacek Jan

Rok: 2019

Druh publikace: článek v odborném periodiku

Název zdroje: Journal of Chemical Technology and Biotechnology

Název nakladatele: John Wiley & Sons Ltd.

Místo vydání: Chichester

Strana od-do: 435-445

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	Směsné Mg-Fe oxidy založené na pyroauritu a jejich aktivita při aldolové condenzaci furfuralu s acetonem: efekt složení oxidu	Byly studovány směsné oxidy Mg-Fe založené na pyroauritu. Jejich strukturní a acidobazické vlastnosti byly zkoumány pomocí několika experimentálních technik. Vlastnosti byly korelovány s katalytickou aktivitou při aldolové kondenzaci furfuralu s acetonem.	Mg-Fe oxidy; prekuryor pyroaurit; aldolová kondenzace; Mg:Fe poměr; silně bazické polohy
eng	Pyroaurite-based Mg-Fe mixed oxides and their activity in aldol condensation of furfural with acetone: effect of oxide composition	Pyroaurite-based Mg-Fe oxides with varying Mg:Fe ratio were studied. The structural and acido-basic properties were examined by number of experimental techniques. The oxide properties were correlated with the catalytic activity in aldol condensation of furfural with acetone. Results Well-developed mesoporous structure was detected for all oxides. Peculiar continuous increase of concentration of basic sites and population of unsaturated strong basic O2- sites was observed with the rising amount of magnesium in the Mg-Fe oxide matrix. A relatively higher concentration of Lewis acid Men+ sites was shown for low Mg:Fe ratios. Unambiguous correlation between conversion of furfural and the density of strong basic sites was proved by combined catalytic and statistical analysis. The contribution of other basic sites was found significantly less important. The impact of both acid and basic sites on the composition of reaction products was discussed. Conclusions Mg-Fe oxides revealed good catalytic performance in the aldol condensation of furfural with acetone where samples with a high Mg:Fe ratio were significantly more basic and had relatively enhanced furfural conversion (nominal Mg:Fe ratio 10; furfural conversion 88% and selectivity to F2Ac 34%; reaction conditions: batch reactor; 50 degrees C; acetone/furfural = 10 mol L-1).	Mg-Fe oxides; pyroaurite precursors; aldol condensation; Mg:Fe ratio; strong basic sites

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