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(N),C,N-Coordinated Heavier Group 13-15 Compounds: Synthesis, Structure and Applications

Autoři: Dostál Libor | Jambor Roman | Aman Michal | Hejda Martin

Rok: 2020

Druh publikace: článek v odborném periodiku

Název zdroje: ChemPlusChem

Název nakladatele: Wiley-VCH

Místo vydání: Weinheim

Strana od-do: 2320-2340

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
cze	(N),C,N-koordinované sloučeniny 13-15 skupiny: Syntéza, Struktura a Aplikace	Byla sepsána studie o současných poznatcích chemii nepřechodných prvků 13 - 15 skupiny.	N,C,N-koordinované; sloučeniny; 13-15; skupiny; Syntéza; Struktura; Aplikace
eng	(N),C,N-Coordinated Heavier Group 13-15 Compounds: Synthesis, Structure and Applications	The aim of this review is to summarize recent achievements in the field of (N),C,N-coordinated group 13-15 compounds not only regarding their synthesis and structure, but mainly focusing on their potential applications. Relevant compounds contain various types of N-coordinating ligands built up on an ortho-(di)substituted phenyl platform. Thus, group 13 and 14 derivatives were used as single-source precursors for the deposition of semiconducting thin films, as building blocks for the preparation of high-molecular polymers with remarkable optical and chemical properties or as compounds with interesting reactivity in hydrometallation processes. Group 15 derivatives function as catalysts in the Mannich reaction, in the allylation of aldehydes or activation of CO2. They were used as transmetallation reagents in transition metal catalysed coupling reactions. The univalent species serve as ligands for transition metals, activate alkynes or alkenes and are utilized as catalysts in the transfer hydrogenation of azo-compounds.	(N); C; N chelating ligands; homogeneous catalysis; intramolecular interactions; main-group elements; metal-containing polymers

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