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Publikace detail

Decorating of push-pull substituted stilbenes with various side groups by Suzuki coupling.
Autoři: Teichmanová Kateřina | Imramovský Aleš | Pauk Karel | Straihorodska Lina | Vala Martin | Luňák Stanislav
Rok: 2022
Druh publikace: ostatní - přednáška nebo poster
Strana od-do: nestránkováno
Tituly:
Jazyk Název Abstrakt Klíčová slova
eng Decorating of push-pull substituted stilbenes with various side groups by Suzuki coupling. Series of all-trans push-pull diphenylamino and carbazole derivates of stilbenes with various electron-donating groups was synthesized. The key intermediate was prepared via Horner-Wadsworth-Emmons reaction between appropriate phosphonate and aldehyde containing two bromine atoms. Bulky side substituents were attached to the main backbone via Suzuki-Miyaura coupling using various boronic acids. Different conditions, such as the type of a base or reaction time were investigated. push-pull substituted stilbenes; Suzuki coupling