Univerzita Pardubice Fakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Substituted diiminoisoindoles as promising ligands for coordination and organometallic chemistry

Autoři: Majerová Stanislava | Švec Petr | Růžička Aleš

Rok: 2023

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Substituted diiminoisoindoles as promising ligands for coordination and organometallic chemistry	Isoindole and its derivatives already found application in multiple fields of chemistry. Among others use as pharmaceuticals, resistant isoindoline and isoindolinone pigments and building blocks for phthalocyanines can be mentioned.1 However, their use as ligands in coordination and organometallic chemistry is still poorly explored. Therefore, we decided to prepare series of isoindole-based protoligands and examine their reactivity with alkali and alkaline earth metals and also with selected transition and post-transition metals. Prepared acyl substituted diiminoisoindoles possess carbonyl group, which allows them typically to form six-member metallacycles as in case of potassium or aluminium. In case of coinage metals and zinc formation of dinuclear complex compounds is observed. Some of the prepared dinuclear complexes even contain remarkable metallophilic interactions