Univerzita PardubiceFakulta chemicko- technologická

Univerzita Pardubice

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Publikace detail

Dianionic Biguanide Complexes Containing Zinc Center(s)

Autoři: Vlk Lukáš | Chlupatý Tomáš | Růžičková Zdeňka | Théron Benjamin | Penouilh Marie-José | Malacea-Kabbara Raluca | Le Gendre Pierre | Růžička Aleš

Rok: 2024

Druh publikace: ostatní - přednáška nebo poster

Strana od-do: nestránkováno

Tituly:

Jazyk	Název	Abstrakt	Klíčová slova
eng	Dianionic Biguanide Complexes Containing Zinc Center(s)	Anionic guanidinates are widely recognized as capable, multi-functional ligand species. Many complexes of main group as well as transition metals have been employed in catalysis and chemical transformations.1 The contrasting scarcity of dianionic guanidinate complexes in the literature makes this topic of high interest. Here we present a robust ligand, suitable for accommodation of two metal nuclei in a homo/heterobimetallic fashion. Interesting reactivity and structural variability of Zn complexes (Scheme 1), originating from the fluxional nature of the n-π conjugated system of joined metallacycles, is depicted.	Dianionic; Biguanide; Complexes; Containing; Zinc; Centers